Journal Article

IMPULSE-2025-00111

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Optically Driven Dynamics of a Mott Insulator‐to‐Metal Transition

Rabinovich, K. S. ; Yaresko, A. N. ; Dawson, R. D. ; Krautloher, M. J. ; Priessnitz, T. ; Mathis, Y.-L. ; Kirilyuk, A. ; Keimer, B. (Corresponding author) ; Boris, A. V. (Corresponding author)

2025
Wiley-VCH Weinheim

Please use a persistent id in citations: doi:10.1002/adfm.202416597

Abstract: Membrane technology offers substantial economic and environmental benefits for energy-intensive chemical separations. Chabazite-type zeolite, possessing a 3-D channel system with molecular-sieving windows, can be an ideal membrane material, but conditions to synthesize zeolite-only membranes limit optimization strategies. Guided by advanced quantum chemistry calculations on inner-pore molecular interactions, zeolite properties are tailored for different separations and optimized particles incorporated in polyimide at very high loadings. A membrane platform is thus created that largely outperforms state-of-the-art membranes for a broad variety of industry-relevant applications, that is, carbon capture, natural gas/biogas purification, hydrocarbon, helium and hydrogen recovery. Accurate size-sieving of gas molecules is realized together with rational determination of optimal gas-zeolite interactions. Crucial for industrial applications, these well-tuned membranes displayed excellent non-aging properties, high flexibility and higher mixed-gas selectivities than ideal-gas selectivities. Moreover, they performed even better at low CO2-partial pressure in CO2-removal and can be made humidity-insensitive.

Keyword(s): Magnetic Materials (1st) ; Magnetism (2nd) ; Materials Science (2nd)

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Contributing Institute(s):

1. SPODI (SPODI)
2. Users (Users)

Experiment(s):

1. SPODI: High resolution powder diffractometer (SR8a)

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Database coverage:
; Clarivate Analytics Master Journal List ; Current Contents - Electronics and Telecommunications Collection ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Ebsco Academic Search ; Essential Science Indicators ; IF >= 15 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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