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| Home > Publications database > Plasmachemical Syntheses of RuF$_{6}$, RhF$_{6}$, and PtF$_{6}$ |
| Home > Publications database > Plasmachemical Syntheses of RuF$_{6}$, RhF$_{6}$, and PtF$_{6}$ |
| Journal Article | IMPULSE-2023-00181 |
; ; ; ;
2023
American Chemical Society
Washington, DC
Please use a persistent id in citations: doi:10.1021/acs.inorgchem.3c02452
Abstract: Starting from the respective metal M, we have synthesized the hexafluorides MF6 of M = Ru, Rh, and Pt by the use of a laser-based heating system and a remote fluorine plasma source using a mixture of Ar and NF$_{3}$ as the feed gas. The formation of the hexafluorides was confirmed by several different spectroscopic methods, including IR, Raman, UV/vis, and NMR spectroscopy. In addition, we present first experimental hints that RuF$_{6}$ is more reactive than PtF$_{6}$, because RuF$_{6}$ is able to oxidize lower fluorides of platinum to PtF$_{6}$.
Keyword(s): Chemical Reactions and Advanced Materials (1st) ; Chemistry (2nd)
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