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2021-01-16
11:29
OpenAccess [FZJ-2021-00263] Journal Article
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Raspberry structures in microgel-silica nanoparticle composite systems
Composite materials consisting of responsive microgels together with additional nanoparticles might provide new and “smart” functionality, e.g. uptake and release of nanoparticles, or special mechanical or rheological properties of a solution. [...]
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2020-12-11
11:29
OpenAccess [FZJ-2020-04970] Journal Article
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Understanding near-surface polymer dynamics by a combination of grazing-incidence neutron scattering and virtual experiments
Neutron spin-echo spectroscopy is a unique experimental method for the investigation of polymer dynamics. The combination of neutron spin-echo spectroscopy with grazing-incidence geometry (GINSES) opens the possibility to probe the dynamics of soft-matter materials in the vicinity of the solid substrate in the time range up to 100 ns. [...]
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2020-10-22
11:28
OpenAccess [FZJ-2020-01375] Journal Article
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Exploring Hidden Local Ordering in Microemulsions with a Weak Directive Second Order Parameter
So far, the near-surface ordering of microemulsions was focused on lamellar ordering while the bulk microemulsion was bicontinuous. In a series of different non-ionic surfactants the near-surface ordering of microemulsions at a hydrophilic silicon surface was studied using grazing incidence small angle neutron scattering. [...]
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2020-09-12
11:28
OpenAccess [FZJ-2020-02821] Journal Article
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The Effects of Temperature and Humidity on the Microstructure of Sulfonated Syndiotactic–polystyrene Ionic Membranes
Membranes 10(8), 187 - () [10.3390/membranes10080187]
Polymeric membranes based on the semi-crystalline syndiotactic–polystyrene (sPS) become hydrophilic, and therefore conductive, following the functionalization of the amorphous phase by the solid-state sulfonation procedure. Because the crystallinity of the material, and thus the mechanical strength of the membranes, is maintained and the resistance to oxidation decomposition can be improved by doping the membranes with fullerenes, the sPS becomes attractive for proton-exchange membranes fuel cells (PEMFC) and energy storage applications. [...]
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2020-08-13
11:28
OpenAccess [FZJ-2020-02354] Journal Article

On the glass transition and correlation functions
Correlation functions are the basis for the understanding of many thermodynamic systems that can be directly observed by scattering experiments. In this manuscript, the correlation functions include the steric repulsion of atoms that also leads to distinct shells of neighbors. [...]
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2020-07-26
11:28
OpenAccess [FZJ-2020-02407] Journal Article
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Prompt gamma rays induced by inelastic scattering of fission neutrons on iron
Prompt gamma rays induced by (n,n′γ) reactions on iron were measured with the instrument FanGaS (Fast Neutron induced Gamma-Ray Spectrometry) operated at the Heinz Maier-Leibnitz Zentrum (MLZ) in Garching. The measurement was performed at an angle of 90° between neutron beam and detector. [...]
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2020-07-10
11:28
OpenAccess [FZJ-2020-01678] Journal Article
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Strain and Electric Field Control of Magnetism in La(1-x)SrxMnO3 Thin Films on Ferroelectric BaTiO3 Substrates
We report on the observation of strain- and magneto-electric coupling in a system consisting of a thin film of ferromagnetic La(1−x)Sr x MnO3 (LSMO, x = 0.5 and 0.3) on a ferroelectric BaTiO3 (BTO) substrate. Pronounced magnetization steps occur at the BTO structural phase transitions [...]
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2020-06-20
11:28
OpenAccess [FZJ-2020-02307] Journal Article
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Self assembled monolayer of silica nanoparticles with improved order by drop casting
RSC Advances 10(31), 18339 - 18347 () [10.1039/D0RA00936A]
This paper reports on the formation of large area, self assembled, highly ordered monolayers of stearyl alcohol grafted silica nanospheres of ≈50 nm diameter on a silicon substrate based on the drop-casting method. Our novel approach to achieve improved order uses stearyl alcohol as an assistant by adding it to the colloidal NanoParticle (NP) dispersion from which the monolayers are formed. [...]
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2020-06-13
11:28
OpenAccess [FZJ-2020-01777] Journal Article
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Multiple Bragg reflection by a thick mosaic crystal. II. Simplified transport equation solved on a grid
The generalized Darwin–Hamilton equations [Wuttke (2014). Acta Cryst. [...]
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2020-06-05
11:28
OpenAccess [FZJ-2020-01766] Journal Article
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In operando monitoring of wood transformation during pretreatment with ionic liquids
Cellulose 27, 4889–4907 () [10.1007/s10570-020-03119-4]
The conversion of lignocellulosic biomass or wood into chemicals still poses a challenge due to the recalcitrance of this composite-like material consisting of lignin, hemicellulose and cellulose. A very high accessibility of cellulose is reported by a pretreatment with ionic liquids that enables high conversion rates by enzymatic hydrolysis. [...]
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